Cathodic Cleavage of alpha-Benzenesulfonylnitriles.

Cathodic hydrodimerization of nitroolefins

Nitroalkenes are easily accessible in high variety by condensation of aldehydes with aliphatic nitroalkanes. They belong to the group of activated alkenes that can be hydrodimerized by cathodic reduction. There are many olefins with different electron withdrawing groups used for cathodic hydrodimerization, but not much is known about the behaviour of the nitro group. Synthetic applications of t...

Expression and Hydroxylamine Cleavage of Thymosin Alpha 1 Concatemer

Human thymosin alpha 1 (Talpha1) is an important peptide in the development and senescence of immunological competence in human, and many studies have reported the expression of this peptide. In this study, we designed and synthesized the Talpha1 gene according to the E. coli codon usage preference and constructed a 6xTalpha1 concatemer. The latter was inserted into an E. coli expression vector...

Specific cleavage of ribosomal RNA caused by alpha sarcin.

Alpha sarcin causes the specific cleavage of RNA from 80S ribosomes and 60S subunits of yeast, but not from the 40S subunits to produce a small RNA fragment. The fragment was also produced on treatment of the 60S subunits of wheat germ ribosomes. The fragment has a molecular weight of 100,000 and is a cleavage product of the large RNA species in the 60S subunits. The fragment is not derived fro...

Maintenance of Cathodic Protection Systems

4.18 Principles of Cathodic Protection

4.18.1 Historical Background 2747 4.18.2 Electrochemical Principles 2748 4.18.2.1 Aqueous Corrosion 2748 4.18.2.2 Cathodic Protection 2748 4.18.2.3 Oxygen Reduction 2749 4.18.2.4 Hydrogen Evolution 2750 4.18.3 Methods of Applying Cathodic Protection 2751 4.18.3.1 Impressed Current Method 2751 4.18.3.2 Sacrificial Anodes 2752 4.18.4 Proof of Protection 2753 4.18.4.1 Steel 2753 4.18.4.2 Other Met...